Ruthenium-catalyzed regioselective allylic amination of 2,3,3-trifluoroallylic carbonates
We demonstrated the ruthenium-catalyzed allylic amination of 2,3,3-trifluoroallylic carbonates with several types of amines. The reactions proceeded with several types of amines, and succeeded in obtaining polyfluorinated terminal alkenes possessing branched allylic amines as a single regioisomer.
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| Veröffentlicht in: | Organic & biomolecular chemistry 2017, Vol.15 (14), p.2938-2946 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | We demonstrated the ruthenium-catalyzed allylic amination of 2,3,3-trifluoroallylic carbonates with several types of amines. The reactions proceeded with several types of amines, and succeeded in obtaining polyfluorinated terminal alkenes possessing branched allylic amines as a single regioisomer. |
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| ISSN: | 1477-0520 1477-0539 |
| DOI: | 10.1039/c7ob00514h |