Gas-phase conversion of the U(VI), Sr, Mo, and Zr compounds in nitrating atmosphere

Gas-phase conversion of the U(VI), Sr, Mo, and Zr compounds in nitrating atmosphere

The gas-phase conversion of U 3 O 8 , MoO 3 , SrO, and their mechanical mixtures, and also of ZrO 2 into water-soluble compounds in the atmosphere of (NO x  + vapor H 2 O) or HNO 3 (vapor) was studied. In the course of gas-phase conversion, U 3 O 8 and SrO transform into water-soluble compounds (nit...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2017-02, Vol.311 (2), p.1023-1034
Hauptverfasser: Kulyukhin, Sergey A., Nevolin, Yurii M., Gorbacheva, Margarita P., Gordeev, Andrey V.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Conversion
Diagnostic Radiology
Electrochemical reactions
Electrochemistry
Hadrons
Heavy Ions
Inorganic Chemistry
Nitrates
Nitration
Nitrogen oxides
Nuclear Chemistry
Nuclear Physics
Physical Chemistry
Short range order
Uranium compounds
Zirconium
Zirconium compounds
Zirconium dioxide
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The gas-phase conversion of U 3 O 8 , MoO 3 , SrO, and their mechanical mixtures, and also of ZrO 2 into water-soluble compounds in the atmosphere of (NO x  + vapor H 2 O) or HNO 3 (vapor) was studied. In the course of gas-phase conversion, U 3 O 8 and SrO transform into water-soluble compounds (nitrates, hydroxonitrates), whereas MoO 3 and ZrO 2 undergo no changes. The principal possibility of separating U from Mo and Zr by gas-phase conversion of the oxides in the atmosphere of (NO x  + vapor H 2 O) or HNO 3 (vapor) was demonstrated.
ISSN:0236-5731
1588-2780
DOI:10.1007/s10967-016-4921-3