Asymmetric Total Synthesis of Lancifodilactone G Acetate

Asymmetric total synthesis of structurally intriguing and highly oxygenated lancifodilactone G acetate (7) has been achieved for the first time in 28 steps from a cheap commodity chemical, 2-(triisopropylsiloxy)-1,3-butadiene.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Chemical Society 2017-04, Vol.139 (16), p.5732-5735
Hauptverfasser:	Liu, Dong-Dong, Sun, Tian-Wen, Wang, Kuang-Yu, Lu, Yong, Zhang, Su-Lei, Li, Yuan-He, Jiang, Yan-Long, Chen, Jia-Hua, Yang, Zhen
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates - chemical synthesis Acetates - chemistry Crystallography, X-Ray Models, Molecular Molecular Conformation Triterpenes - chemical synthesis Triterpenes - chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Asymmetric total synthesis of structurally intriguing and highly oxygenated lancifodilactone G acetate (7) has been achieved for the first time in 28 steps from a cheap commodity chemical, 2-(triisopropylsiloxy)-1,3-butadiene.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/jacs.7b02561