Electrically Rechargeable Zinc–Air Batteries: Progress, Challenges, and Perspectives

Zinc–air batteries have attracted much attention and received revived research efforts recently due to their high energy density, which makes them a promising candidate for emerging mobile and electronic applications. Besides their high energy density, they also demonstrate other desirable characteristics, such as abundant raw materials, environmental friendliness, safety, and low cost. Here, the reaction mechanism of electrically rechargeable zinc–air batteries is discussed, different battery configurations are compared, and an in depth discussion is offered of the major issues that affect individual cellular components, along with respective strategies to alleviate these issues to enhance battery performance. Additionally, a section dedicated to battery‐testing techniques and corresponding recommendations for best practices are included. Finally, a general perspective on the current limitations, recent application‐targeted developments, and recommended future research directions to prolong the lifespan of electrically rechargeable zinc–air batteries is provided. Electrically rechargeable zinc–air batteries lie at the heart of emerging energy‐storage technologies, such as electric vehicles and wearable devices, benefiting from their high energy density and environmental friendliness. The current status and challenges faced by electrically rechargeable zinc–air batteries are discussed in detail. The potential solutions to these problems are thoroughly investigated.