Construction of 2D covalent organic frameworks by taking advantage of the variable orientation of imine bonds

Construction of 2D covalent organic frameworks by taking advantage of the variable orientation of imine bonds

A model system has been established to construct two-dimensional (2D) covalent organic frameworks (COFs) by taking advantage of the variable orientation of imine bonds. During the assembly process, the imine bonds adopt an unprecedented heterodromous orientation to facilitate the formation of the CO...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-02, Vol.53 (16), p.2431-2434
Hauptverfasser: Xu, Shun-Qi, Liang, Rong-Ran, Zhan, Tian-Guang, Qi, Qiao-Yan, Zhao, Xin
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Chemical bonds
Covalence
Formations
Imines
Mathematical models
Orientation
Two dimensional models
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Zusammenfassung:A model system has been established to construct two-dimensional (2D) covalent organic frameworks (COFs) by taking advantage of the variable orientation of imine bonds. During the assembly process, the imine bonds adopt an unprecedented heterodromous orientation to facilitate the formation of the COFs.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc09906h