Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions

Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions

A two-step synthetic approach for the production of renewable 1,3-pentadiene was reported: xylitol deoxydehydration (DODH) by formic acid to 2,4-pentadien-1-ol, 1-formate (2E), followed by deoxygenation to 1,3-pentadiene over Pd/C. The overall carbon yield of 1,3-pentadiene reached 51.8% under the o...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2017, Vol.19 (3), p.638-642
Hauptverfasser: Sun, Ruiyan, Zheng, Mingyuan, Li, Xinsheng, Pang, Jifeng, Wang, Aiqin, Wang, Xiaodong, Zhang, Tao
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Sprache:eng
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Carbon
Deoxygenation
Formic acid
Palladium
Xylitol
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container_title Green chemistry : an international journal and green chemistry resource : GC
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creator Sun, Ruiyan
Zheng, Mingyuan
Li, Xinsheng
Pang, Jifeng
Wang, Aiqin
Wang, Xiaodong
Zhang, Tao
description A two-step synthetic approach for the production of renewable 1,3-pentadiene was reported: xylitol deoxydehydration (DODH) by formic acid to 2,4-pentadien-1-ol, 1-formate (2E), followed by deoxygenation to 1,3-pentadiene over Pd/C. The overall carbon yield of 1,3-pentadiene reached 51.8% under the optimized conditions.
doi_str_mv 10.1039/c6gc02868c
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Carbon
Deoxygenation
Formic acid
Palladium
Xylitol
title Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions
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