Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions

Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions

A two-step synthetic approach for the production of renewable 1,3-pentadiene was reported: xylitol deoxydehydration (DODH) by formic acid to 2,4-pentadien-1-ol, 1-formate (2E), followed by deoxygenation to 1,3-pentadiene over Pd/C. The overall carbon yield of 1,3-pentadiene reached 51.8% under the o...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2017, Vol.19 (3), p.638-642
Hauptverfasser: Sun, Ruiyan, Zheng, Mingyuan, Li, Xinsheng, Pang, Jifeng, Wang, Aiqin, Wang, Xiaodong, Zhang, Tao
Format: Artikel
Sprache:eng
Schlagworte:
Carbon
Deoxygenation
Formic acid
Palladium
Xylitol
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Zusammenfassung:A two-step synthetic approach for the production of renewable 1,3-pentadiene was reported: xylitol deoxydehydration (DODH) by formic acid to 2,4-pentadien-1-ol, 1-formate (2E), followed by deoxygenation to 1,3-pentadiene over Pd/C. The overall carbon yield of 1,3-pentadiene reached 51.8% under the optimized conditions.
ISSN:1463-9262
1463-9270
DOI:10.1039/c6gc02868c