Control of bulk homochirality and proton conductivity in isostructural chiral metal-organic frameworks

Control of bulk homochirality and proton conductivity in isostructural chiral metal-organic frameworks

We have demonstrated for the first time that isostructural homochiral metal-organic frameworks (MOFs) can be synthesized directly from chiral ligands and indirectly from achiral ligands via spontaneous resolution combined with cooperative chirality induction, respectively. Moreover, the usage of dif...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (11), p.1892-1895
Hauptverfasser: Song, Bai-Qiao, Chen, Da-Qin, Ji, Zhenguo, Tang, Junhong, Wang, Xin-Long, Zang, Hong-Ying, Su, Zhong-Min
Format: Artikel
Sprache:eng
Schlagworte:
Chirality
Ligands
Metal-organic frameworks
Proton conduction
Spontaneous
Synthesis
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Zusammenfassung:We have demonstrated for the first time that isostructural homochiral metal-organic frameworks (MOFs) can be synthesized directly from chiral ligands and indirectly from achiral ligands via spontaneous resolution combined with cooperative chirality induction, respectively. Moreover, the usage of different ligands leads to distinct proton conduction behaviors.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc07729c