Comparison study on photocatalytic oxidation of pharmaceuticals by TiO2-Fe and TiO2-reduced graphene oxide nanocomposites immobilized on optical fibers

[Display omitted] •Incorporating rGO or Fe3+ ions in TiO2 photocatalyst could enhance photocatalysis.•TiO2-rGO exhibited higher photocatalytic activity under UV irradiation.•TiO2-Fe demonstrated more suitable for visible light irradiation.•Reduced recombination rate contributed to enhanced photocatalysis of TiO2-rGO.•Narrower band gap accounted for increased photocatalytic activity of TiO2-Fe. Incorporating reduced graphene oxide (rGO) or Fe3+ ions in TiO2 photocatalyst could enhance photocatalytic degradation of organic contaminants in aqueous solutions. This study characterized the photocatalytic activities of TiO2-Fe and TiO2-rGO nanocomposites immobilized on optical fibers synthesized by polymer assisted hydrothermal deposition method. The photocatalysts presented a mixture phase of anatase and rutile in the TiO2-rGO and TiO2-Fe nanocomposites. Doping Fe into TiO2 particles (2.40eV) could reduce more band gap energy than incorporating rGO (2.85eV), thereby enhancing utilization efficiency of visible light. Incorporating Fe and rGO in TiO2 decreased significantly the intensity of TiO2 photoluminescence signals and enhanced the separation rate of photo-induced charge carriers. Photocatalytic performance of the synthesized nanocomposites was measured by the degradation of three pharmaceuticals under UV and visible light irradiation, including carbamazepine, ibuprofen, and sulfamethoxazole. TiO2-rGO exhibited higher photocatalytic activity for the degradation of pharmaceuticals under UV irradiation, while TiO2-Fe demonstrated more suitable for visible light oxidation. The results suggested that the enhanced photocatalytic performance of TiO2-rGO could be attributed to reduced recombination rate of photoexcited electrons-hole pairs, but for TiO2-Fe nanocomposite, narrower band gap would contribute to increased photocatalytic activity.