A compact form for the analytic description of temperature dependence of saturation vapor pressure over plane surfaces of water and ice

A possibility is studied of extending the range of action of the simple three-parameter formula (ITS-90 scale) proposed in the previous work of the author [2] for the dependence of saturation vapor pressure E on temperature T within the range of 250 to 490 K. The results demonstrated that the depend...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian meteorology and hydrology 2017, Vol.42 (1), p.27-37
1. Verfasser: Romanov, N. P.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A possibility is studied of extending the range of action of the simple three-parameter formula (ITS-90 scale) proposed in the previous work of the author [2] for the dependence of saturation vapor pressure E on temperature T within the range of 250 to 490 K. The results demonstrated that the dependence ln[ E ( T )/ E ( T bas )] = ( T - T bas )[ A - B ( T - T bas ) + C ( T - T bas ) 2 ]/ T with four sets of coefficients A , B , and C obtained using one base temperature Tbas equal to the temperature of triple point of water T t = 273.16 K and two additional base values T bas2 = 473.16 K and T bas3 = 623.16 K makes it possible to approximate rather accurately the initial experimental and computed data in the temperature range from the point of homogeneous freezing of 235 K to the critical temperature of 647 K for liquid water and from 193 K to T t for ice. A procedure used for obtaining the inverse function T ( E ) by solving the third-degree algebraic equation is validated. A hypothesis is proposed for the physical substantiation of additional base points in the form of “a noticeable appearance of dimers at the point T bas2 and their 100% concentration at the temperature T bas3 .”
ISSN:1068-3739
1934-8096
DOI:10.3103/S1068373917010046