Sub-micron pore size tailoring for efficient chiral discrimination

Sub-micron pore size tailoring for efficient chiral discrimination

Adsorption studies in microporous organically pillared layered silicates (MOPS) show that precise control of micropore size in the sub-Ångström range is crucial for chiral discrimination. The highly modular character of MOPS generally allows for an optimization of guest recognition without the need...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (6), p.1072-1075
Hauptverfasser: Herling, Markus M, Lacher, Ulrike, Rieß, Martin, Seibt, Sebastian, Schwedes, Mathias, Kalo, Hussein, Schobert, Rainer, Breu, Josef
Format: Artikel
Sprache:eng
Schlagworte:
Character recognition
Discrimination
Mopping
Optimization
Pore size
Porosity
Silicates
Topology
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Zusammenfassung:Adsorption studies in microporous organically pillared layered silicates (MOPS) show that precise control of micropore size in the sub-Ångström range is crucial for chiral discrimination. The highly modular character of MOPS generally allows for an optimization of guest recognition without the need to explore different framework topologies.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc09484h