Sole Chemical Confinement of Polysulfides on Nonporous Nitrogen/Oxygen Dual‐Doped Carbon at the Kilogram Scale for Lithium–Sulfur Batteries

The exploration of inexpensive, facile, and large‐scale methods to prepare carbon scaffolds for high sulfur loadings is crucial for the advancement of Li–S batteries (LSBs). Herein, the authors report a new nitrogen and oxygen in situ dual‐doped nonporous carbonaceous material (NONPCM) that is composed of a myriad of graphene‐analogous particles. Importantly, NONPCM could be fabricated on a kilogram scale via inexpensive and green hydrothermal‐carbonization‐combined methods. Many active sites on the NONPCM surface are accessible for the efficient surface‐chemistry confinement of guest sulfur and its discharge product; this confinement is exclusive of physical entrapment, considering the low surface area. Electrochemical examination demonstrates excellent cycle stability and rate performance of the NONPCM (K)/S composite, even with a sulfur loading of 80 or 90 wt%. Hence, the scaffolds for LSBs exhibit potential for industrialization through further optimization and expansion of the present synthesis. A new nitrogen and oxygen in situ dual‐doped nonporous carbonaceous material (NONPCM): NONPCM, composed of a myriad of graphene‐analogous particles, is for the first time fabricated on a kilogram scale by a green hydrothermal method. Considering the favorable preparation and remarkable electrochemical behavior, NONPCM is a very promising candidate for sulfur scaffolds to bridge the practical applications of Li–S batteries.