Preparation of Electrophilic Trifluromethylthio Reagents from Nucleophilic Tetramethylammonium Trifluoromethylthiolate

Preparation of Electrophilic Trifluromethylthio Reagents from Nucleophilic Tetramethylammonium Trifluoromethylthiolate

A straightforward synthetic entry to the principal classes of electrophilic trifluoromethylthiolating agents is presented. It draws on inexpensive, shelf‐stable tetramethylammonium trifluoromethylthiolate (Me4N–SCF3) as the SCF3 source in the place of stoichiometric coinage metal‐SCF3 complexes....

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Veröffentlicht in:Advanced synthesis & catalysis 2017-01, Vol.359 (2), p.250-254
Hauptverfasser: Kovács, Szabolcs, Bayarmagnai, Bilguun, Goossen, Lukas J.
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Coordination compounds
C–H functionalization
fluorine
Reagents
sulfur
Synthesis (chemistry)
synthetic methods
trifluoromethylthiolation
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Zusammenfassung:A straightforward synthetic entry to the principal classes of electrophilic trifluoromethylthiolating agents is presented. It draws on inexpensive, shelf‐stable tetramethylammonium trifluoromethylthiolate (Me4N–SCF3) as the SCF3 source in the place of stoichiometric coinage metal‐SCF3 complexes.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201601298