Monoterpene emissions and carbonyl compound air concentrations during the blooming period of rape ( Brassica napus)
An increasing percentage of agricultural land in Germany is used for oil seed plants. Hence, rape has become an important agricultural plant (in Saxony 1998: 12% of the farmland) in the recent years. During flowering of rape along with intensive radiation and high temperatures, a higher production a...
Gespeichert in:
Veröffentlicht in: | Chemosphere (Oxford) 2002-12, Vol.49 (10), p.1247-1256 |
---|---|
Hauptverfasser: | , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 1256 |
---|---|
container_issue | 10 |
container_start_page | 1247 |
container_title | Chemosphere (Oxford) |
container_volume | 49 |
creator | Müller, Konrad Pelzing, Matthias Gnauk, Thomas Kappe, Anett Teichmann, Ulrich Spindler, Gerald Haferkorn, Sylvia Jahn, Yvonne Herrmann, Hartmut |
description | An increasing percentage of agricultural land in Germany is used for oil seed plants. Hence, rape has become an important agricultural plant (in Saxony 1998: 12% of the farmland) in the recent years. During flowering of rape along with intensive radiation and high temperatures, a higher production and emission of biogenic VOC was observed. The emissions of terpenes were determined and more importantly, high concentrations of organic carbonyl compounds were observed during this field experiment. All measurements of interest have been carried out during two selected days with optimal weather conditions. It is found that the origin or the mechanism of formation of different group of compounds had strong influence on the day to day variation of their concentrations. The emission flux of terpenes from flowering rape plants was determined to be 16–32 μg
h
−1
m
−2 (30–60 ng
h
−1 per g dry plant––540–1080 ng
h
−1 per plant), in total. Limonene, α-thujene and sabinene were the most important compounds (about 60% of total terpenes). For limonene and sabinene reference emission rates (
M
S) and temperature coefficients were determined:
β
limonene=0.108 K
−1 and
M
S=14.57 μg
h
−1
m
−2;
β
sabinene=0.095 K
−1 and
M
S=5.39 μg
h
−1
m
−2.
The detected carbonyl compound concentrations were unexpectedly high (maximum formaldehyde concentration was 18.1 ppbv and 3.4 ppbv for butyraldehyde) for an open field. Possible reasons for these concentrations are the combination of primary emission from the plants induced by high temperature and high ozone stress, the secondary formation from biogenically and advected anthropogenically emitted VOC at high radiation intensities and furthered by the low wind speeds at this time. |
doi_str_mv | 10.1016/S0045-6535(02)00610-0 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1875859024</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0045653502006100</els_id><sourcerecordid>1875859024</sourcerecordid><originalsourceid>FETCH-LOGICAL-c521t-73c2b936e0d645f51339c2dea1fbc6bc217f0f417999e4c95000033dc019379a3</originalsourceid><addsrcrecordid>eNqFkUtv1TAQhS0EoreFnwDyBnS7CIztOL5eVVCVh1TEAlhbjj0Bo8QOdoLUf4_vQ3QHq9GMvjP2nEPIMwavGLDu9ReAVjadFHIL_BKgY9DAA7JhO6UbxvXuIdn8Rc7IeSk_AapQ6sfkjPF2pxVnG1I-pZgWzDNGpDiFUkKKhdroqbO5T_FupC5Nc1rrxIZcm-gwLtkuB9CvOcTvdPmBtB9TmvbNjDkkT9NAs52RbunbbOteZ2m081oun5BHgx0LPj3VC_Lt3c3X6w_N7ef3H6_f3DZOcrY0Sjjea9Eh-K6Vg2RCaMc9Wjb0rusdZ2qAoWVKa42t07LeB0J4B0wLpa24INvj3jmnXyuWxdT7HI6jjZjWYqpVcic18LaiL_-Nqk51TMgKyiPociol42DmHCab7wwDsw_GHIIxe9cNcHMIxkDVPT89sPYT-nvVKYkKvDgBtjg7DtlGF8o91wJoJbrKXR05rM79DphNcQFrJj5kdIvxKfznK38AkrSqUw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>17676135</pqid></control><display><type>article</type><title>Monoterpene emissions and carbonyl compound air concentrations during the blooming period of rape ( Brassica napus)</title><source>MEDLINE</source><source>Elsevier ScienceDirect Journals</source><creator>Müller, Konrad ; Pelzing, Matthias ; Gnauk, Thomas ; Kappe, Anett ; Teichmann, Ulrich ; Spindler, Gerald ; Haferkorn, Sylvia ; Jahn, Yvonne ; Herrmann, Hartmut</creator><creatorcontrib>Müller, Konrad ; Pelzing, Matthias ; Gnauk, Thomas ; Kappe, Anett ; Teichmann, Ulrich ; Spindler, Gerald ; Haferkorn, Sylvia ; Jahn, Yvonne ; Herrmann, Hartmut</creatorcontrib><description>An increasing percentage of agricultural land in Germany is used for oil seed plants. Hence, rape has become an important agricultural plant (in Saxony 1998: 12% of the farmland) in the recent years. During flowering of rape along with intensive radiation and high temperatures, a higher production and emission of biogenic VOC was observed. The emissions of terpenes were determined and more importantly, high concentrations of organic carbonyl compounds were observed during this field experiment. All measurements of interest have been carried out during two selected days with optimal weather conditions. It is found that the origin or the mechanism of formation of different group of compounds had strong influence on the day to day variation of their concentrations. The emission flux of terpenes from flowering rape plants was determined to be 16–32 μg
h
−1
m
−2 (30–60 ng
h
−1 per g dry plant––540–1080 ng
h
−1 per plant), in total. Limonene, α-thujene and sabinene were the most important compounds (about 60% of total terpenes). For limonene and sabinene reference emission rates (
M
S) and temperature coefficients were determined:
β
limonene=0.108 K
−1 and
M
S=14.57 μg
h
−1
m
−2;
β
sabinene=0.095 K
−1 and
M
S=5.39 μg
h
−1
m
−2.
The detected carbonyl compound concentrations were unexpectedly high (maximum formaldehyde concentration was 18.1 ppbv and 3.4 ppbv for butyraldehyde) for an open field. Possible reasons for these concentrations are the combination of primary emission from the plants induced by high temperature and high ozone stress, the secondary formation from biogenically and advected anthropogenically emitted VOC at high radiation intensities and furthered by the low wind speeds at this time.</description><identifier>ISSN: 0045-6535</identifier><identifier>EISSN: 1879-1298</identifier><identifier>DOI: 10.1016/S0045-6535(02)00610-0</identifier><identifier>PMID: 12489721</identifier><identifier>CODEN: CMSHAF</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Aldehyde mixing ratios ; Applied sciences ; Atmospheric pollution ; Brassica ; Chromatography, High Pressure Liquid ; Disinfectants - analysis ; Dispersed sources and other ; Environmental Monitoring ; Exact sciences and technology ; Flowers - chemistry ; Formaldehyde - analysis ; GC–MS ; Hot Temperature ; HPLC ; Monoterpene emission flow rates ; Monoterpenes - analysis ; Pollution ; Pollution sources. Measurement results ; Seasons ; Sunlight ; Volatilization ; Wind</subject><ispartof>Chemosphere (Oxford), 2002-12, Vol.49 (10), p.1247-1256</ispartof><rights>2002 Elsevier Science Ltd</rights><rights>2003 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c521t-73c2b936e0d645f51339c2dea1fbc6bc217f0f417999e4c95000033dc019379a3</citedby><cites>FETCH-LOGICAL-c521t-73c2b936e0d645f51339c2dea1fbc6bc217f0f417999e4c95000033dc019379a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0045653502006100$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65534</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14009736$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/12489721$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Müller, Konrad</creatorcontrib><creatorcontrib>Pelzing, Matthias</creatorcontrib><creatorcontrib>Gnauk, Thomas</creatorcontrib><creatorcontrib>Kappe, Anett</creatorcontrib><creatorcontrib>Teichmann, Ulrich</creatorcontrib><creatorcontrib>Spindler, Gerald</creatorcontrib><creatorcontrib>Haferkorn, Sylvia</creatorcontrib><creatorcontrib>Jahn, Yvonne</creatorcontrib><creatorcontrib>Herrmann, Hartmut</creatorcontrib><title>Monoterpene emissions and carbonyl compound air concentrations during the blooming period of rape ( Brassica napus)</title><title>Chemosphere (Oxford)</title><addtitle>Chemosphere</addtitle><description>An increasing percentage of agricultural land in Germany is used for oil seed plants. Hence, rape has become an important agricultural plant (in Saxony 1998: 12% of the farmland) in the recent years. During flowering of rape along with intensive radiation and high temperatures, a higher production and emission of biogenic VOC was observed. The emissions of terpenes were determined and more importantly, high concentrations of organic carbonyl compounds were observed during this field experiment. All measurements of interest have been carried out during two selected days with optimal weather conditions. It is found that the origin or the mechanism of formation of different group of compounds had strong influence on the day to day variation of their concentrations. The emission flux of terpenes from flowering rape plants was determined to be 16–32 μg
h
−1
m
−2 (30–60 ng
h
−1 per g dry plant––540–1080 ng
h
−1 per plant), in total. Limonene, α-thujene and sabinene were the most important compounds (about 60% of total terpenes). For limonene and sabinene reference emission rates (
M
S) and temperature coefficients were determined:
β
limonene=0.108 K
−1 and
M
S=14.57 μg
h
−1
m
−2;
β
sabinene=0.095 K
−1 and
M
S=5.39 μg
h
−1
m
−2.
The detected carbonyl compound concentrations were unexpectedly high (maximum formaldehyde concentration was 18.1 ppbv and 3.4 ppbv for butyraldehyde) for an open field. Possible reasons for these concentrations are the combination of primary emission from the plants induced by high temperature and high ozone stress, the secondary formation from biogenically and advected anthropogenically emitted VOC at high radiation intensities and furthered by the low wind speeds at this time.</description><subject>Aldehyde mixing ratios</subject><subject>Applied sciences</subject><subject>Atmospheric pollution</subject><subject>Brassica</subject><subject>Chromatography, High Pressure Liquid</subject><subject>Disinfectants - analysis</subject><subject>Dispersed sources and other</subject><subject>Environmental Monitoring</subject><subject>Exact sciences and technology</subject><subject>Flowers - chemistry</subject><subject>Formaldehyde - analysis</subject><subject>GC–MS</subject><subject>Hot Temperature</subject><subject>HPLC</subject><subject>Monoterpene emission flow rates</subject><subject>Monoterpenes - analysis</subject><subject>Pollution</subject><subject>Pollution sources. Measurement results</subject><subject>Seasons</subject><subject>Sunlight</subject><subject>Volatilization</subject><subject>Wind</subject><issn>0045-6535</issn><issn>1879-1298</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUtv1TAQhS0EoreFnwDyBnS7CIztOL5eVVCVh1TEAlhbjj0Bo8QOdoLUf4_vQ3QHq9GMvjP2nEPIMwavGLDu9ReAVjadFHIL_BKgY9DAA7JhO6UbxvXuIdn8Rc7IeSk_AapQ6sfkjPF2pxVnG1I-pZgWzDNGpDiFUkKKhdroqbO5T_FupC5Nc1rrxIZcm-gwLtkuB9CvOcTvdPmBtB9TmvbNjDkkT9NAs52RbunbbOteZ2m081oun5BHgx0LPj3VC_Lt3c3X6w_N7ef3H6_f3DZOcrY0Sjjea9Eh-K6Vg2RCaMc9Wjb0rusdZ2qAoWVKa42t07LeB0J4B0wLpa24INvj3jmnXyuWxdT7HI6jjZjWYqpVcic18LaiL_-Nqk51TMgKyiPociol42DmHCab7wwDsw_GHIIxe9cNcHMIxkDVPT89sPYT-nvVKYkKvDgBtjg7DtlGF8o91wJoJbrKXR05rM79DphNcQFrJj5kdIvxKfznK38AkrSqUw</recordid><startdate>20021201</startdate><enddate>20021201</enddate><creator>Müller, Konrad</creator><creator>Pelzing, Matthias</creator><creator>Gnauk, Thomas</creator><creator>Kappe, Anett</creator><creator>Teichmann, Ulrich</creator><creator>Spindler, Gerald</creator><creator>Haferkorn, Sylvia</creator><creator>Jahn, Yvonne</creator><creator>Herrmann, Hartmut</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TG</scope><scope>KL.</scope></search><sort><creationdate>20021201</creationdate><title>Monoterpene emissions and carbonyl compound air concentrations during the blooming period of rape ( Brassica napus)</title><author>Müller, Konrad ; Pelzing, Matthias ; Gnauk, Thomas ; Kappe, Anett ; Teichmann, Ulrich ; Spindler, Gerald ; Haferkorn, Sylvia ; Jahn, Yvonne ; Herrmann, Hartmut</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c521t-73c2b936e0d645f51339c2dea1fbc6bc217f0f417999e4c95000033dc019379a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Aldehyde mixing ratios</topic><topic>Applied sciences</topic><topic>Atmospheric pollution</topic><topic>Brassica</topic><topic>Chromatography, High Pressure Liquid</topic><topic>Disinfectants - analysis</topic><topic>Dispersed sources and other</topic><topic>Environmental Monitoring</topic><topic>Exact sciences and technology</topic><topic>Flowers - chemistry</topic><topic>Formaldehyde - analysis</topic><topic>GC–MS</topic><topic>Hot Temperature</topic><topic>HPLC</topic><topic>Monoterpene emission flow rates</topic><topic>Monoterpenes - analysis</topic><topic>Pollution</topic><topic>Pollution sources. Measurement results</topic><topic>Seasons</topic><topic>Sunlight</topic><topic>Volatilization</topic><topic>Wind</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Müller, Konrad</creatorcontrib><creatorcontrib>Pelzing, Matthias</creatorcontrib><creatorcontrib>Gnauk, Thomas</creatorcontrib><creatorcontrib>Kappe, Anett</creatorcontrib><creatorcontrib>Teichmann, Ulrich</creatorcontrib><creatorcontrib>Spindler, Gerald</creatorcontrib><creatorcontrib>Haferkorn, Sylvia</creatorcontrib><creatorcontrib>Jahn, Yvonne</creatorcontrib><creatorcontrib>Herrmann, Hartmut</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><jtitle>Chemosphere (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Müller, Konrad</au><au>Pelzing, Matthias</au><au>Gnauk, Thomas</au><au>Kappe, Anett</au><au>Teichmann, Ulrich</au><au>Spindler, Gerald</au><au>Haferkorn, Sylvia</au><au>Jahn, Yvonne</au><au>Herrmann, Hartmut</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Monoterpene emissions and carbonyl compound air concentrations during the blooming period of rape ( Brassica napus)</atitle><jtitle>Chemosphere (Oxford)</jtitle><addtitle>Chemosphere</addtitle><date>2002-12-01</date><risdate>2002</risdate><volume>49</volume><issue>10</issue><spage>1247</spage><epage>1256</epage><pages>1247-1256</pages><issn>0045-6535</issn><eissn>1879-1298</eissn><coden>CMSHAF</coden><abstract>An increasing percentage of agricultural land in Germany is used for oil seed plants. Hence, rape has become an important agricultural plant (in Saxony 1998: 12% of the farmland) in the recent years. During flowering of rape along with intensive radiation and high temperatures, a higher production and emission of biogenic VOC was observed. The emissions of terpenes were determined and more importantly, high concentrations of organic carbonyl compounds were observed during this field experiment. All measurements of interest have been carried out during two selected days with optimal weather conditions. It is found that the origin or the mechanism of formation of different group of compounds had strong influence on the day to day variation of their concentrations. The emission flux of terpenes from flowering rape plants was determined to be 16–32 μg
h
−1
m
−2 (30–60 ng
h
−1 per g dry plant––540–1080 ng
h
−1 per plant), in total. Limonene, α-thujene and sabinene were the most important compounds (about 60% of total terpenes). For limonene and sabinene reference emission rates (
M
S) and temperature coefficients were determined:
β
limonene=0.108 K
−1 and
M
S=14.57 μg
h
−1
m
−2;
β
sabinene=0.095 K
−1 and
M
S=5.39 μg
h
−1
m
−2.
The detected carbonyl compound concentrations were unexpectedly high (maximum formaldehyde concentration was 18.1 ppbv and 3.4 ppbv for butyraldehyde) for an open field. Possible reasons for these concentrations are the combination of primary emission from the plants induced by high temperature and high ozone stress, the secondary formation from biogenically and advected anthropogenically emitted VOC at high radiation intensities and furthered by the low wind speeds at this time.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><pmid>12489721</pmid><doi>10.1016/S0045-6535(02)00610-0</doi><tpages>10</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0045-6535 |
ispartof | Chemosphere (Oxford), 2002-12, Vol.49 (10), p.1247-1256 |
issn | 0045-6535 1879-1298 |
language | eng |
recordid | cdi_proquest_miscellaneous_1875859024 |
source | MEDLINE; Elsevier ScienceDirect Journals |
subjects | Aldehyde mixing ratios Applied sciences Atmospheric pollution Brassica Chromatography, High Pressure Liquid Disinfectants - analysis Dispersed sources and other Environmental Monitoring Exact sciences and technology Flowers - chemistry Formaldehyde - analysis GC–MS Hot Temperature HPLC Monoterpene emission flow rates Monoterpenes - analysis Pollution Pollution sources. Measurement results Seasons Sunlight Volatilization Wind |
title | Monoterpene emissions and carbonyl compound air concentrations during the blooming period of rape ( Brassica napus) |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-17T21%3A05%3A24IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Monoterpene%20emissions%20and%20carbonyl%20compound%20air%20concentrations%20during%20the%20blooming%20period%20of%20rape%20(%20Brassica%20napus)&rft.jtitle=Chemosphere%20(Oxford)&rft.au=M%C3%BCller,%20Konrad&rft.date=2002-12-01&rft.volume=49&rft.issue=10&rft.spage=1247&rft.epage=1256&rft.pages=1247-1256&rft.issn=0045-6535&rft.eissn=1879-1298&rft.coden=CMSHAF&rft_id=info:doi/10.1016/S0045-6535(02)00610-0&rft_dat=%3Cproquest_cross%3E1875859024%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=17676135&rft_id=info:pmid/12489721&rft_els_id=S0045653502006100&rfr_iscdi=true |