Synthesis of Ring-Fused 1‑Benzazepines via [1,5]-Hydride Shift/7-Endo Cyclization Sequences

Synthesis of Ring-Fused 1‑Benzazepines via [1,5]-Hydride Shift/7-Endo Cyclization Sequences

Synthesis of 1-benzazepines has been achieved via a [1,5]-hydride shift/7-endo cyclization sequence. The focus of this research is a direct transformation of 2-(aryl)­cyclopropane 1,1-diester derivatives into 1-benzazepines using a cyclopropane moiety as the hydride acceptor in internal redox reacti...

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Veröffentlicht in:Organic letters 2017-03, Vol.19 (6), p.1334-1337
Hauptverfasser: Suh, Chang Won, Kwon, Su Jin, Kim, Dae Young
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Kwon, Su Jin
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description Synthesis of 1-benzazepines has been achieved via a [1,5]-hydride shift/7-endo cyclization sequence. The focus of this research is a direct transformation of 2-(aryl)­cyclopropane 1,1-diester derivatives into 1-benzazepines using a cyclopropane moiety as the hydride acceptor in internal redox reactions.
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title Synthesis of Ring-Fused 1‑Benzazepines via [1,5]-Hydride Shift/7-Endo Cyclization Sequences
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