Cu( ii ) complex of a new isoindole derivative: structure, catecholase like activity, antimicrobial properties and bio-molecular interactions
An isoindole based Cu( ii ) complex, [ Cu(PICPH)Cl2 ], was synthesized in situ by reacting copper( ii ) chloride with a pyridine derived ligand, PICPH. The complex was characterized by spectroscopic techniques while its structure was confirmed by single crystal X-ray diffraction analysis. The comple...
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| Veröffentlicht in: | New journal of chemistry 2016, Vol.40 (12), p.10094-10099 |
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| container_title | New journal of chemistry |
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| creator | Adhikari, Sangita Lohar, Sisir Kumari, Babli Banerjee, Aparna Bandopadhyay, Rajib Matalobos, Jesús Sanmartín Das, Debasis |
| description | An isoindole based Cu(
ii
) complex, [
Cu(PICPH)Cl2
], was synthesized
in situ
by reacting copper(
ii
) chloride with a pyridine derived ligand, PICPH. The complex was characterized by spectroscopic techniques while its structure was confirmed by single crystal X-ray diffraction analysis. The complex has a trigonal bipyramid geometry containing both five- and seven-member chelate rings. It shows catecholase-like activity. Interaction of the complex with a bio-relevant antipyrine derivative (
ANNAP
) was studied using fluorescence spectroscopy. DFT studies unfold the energetics associated with PICPH, [
Cu(PICPH)Cl2
] and the adduct between [
Cu(PICPH)Cl2
] and
ANNAP
. Antimicrobial activities of the compounds were also studied. |
| doi_str_mv | 10.1039/C6NJ02193J |
| format | Article |
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ii
) complex, [
Cu(PICPH)Cl2
], was synthesized
in situ
by reacting copper(
ii
) chloride with a pyridine derived ligand, PICPH. The complex was characterized by spectroscopic techniques while its structure was confirmed by single crystal X-ray diffraction analysis. The complex has a trigonal bipyramid geometry containing both five- and seven-member chelate rings. It shows catecholase-like activity. Interaction of the complex with a bio-relevant antipyrine derivative (
ANNAP
) was studied using fluorescence spectroscopy. DFT studies unfold the energetics associated with PICPH, [
Cu(PICPH)Cl2
] and the adduct between [
Cu(PICPH)Cl2
] and
ANNAP
. Antimicrobial activities of the compounds were also studied.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/C6NJ02193J</identifier><language>eng</language><ispartof>New journal of chemistry, 2016, Vol.40 (12), p.10094-10099</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c264t-ce770c47337b76f733c6adc092d02a8dfdb1847eb22d6a949a48604328fbd1453</citedby><cites>FETCH-LOGICAL-c264t-ce770c47337b76f733c6adc092d02a8dfdb1847eb22d6a949a48604328fbd1453</cites><orcidid>0000-0002-9971-4657</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Adhikari, Sangita</creatorcontrib><creatorcontrib>Lohar, Sisir</creatorcontrib><creatorcontrib>Kumari, Babli</creatorcontrib><creatorcontrib>Banerjee, Aparna</creatorcontrib><creatorcontrib>Bandopadhyay, Rajib</creatorcontrib><creatorcontrib>Matalobos, Jesús Sanmartín</creatorcontrib><creatorcontrib>Das, Debasis</creatorcontrib><title>Cu( ii ) complex of a new isoindole derivative: structure, catecholase like activity, antimicrobial properties and bio-molecular interactions</title><title>New journal of chemistry</title><description>An isoindole based Cu(
ii
) complex, [
Cu(PICPH)Cl2
], was synthesized
in situ
by reacting copper(
ii
) chloride with a pyridine derived ligand, PICPH. The complex was characterized by spectroscopic techniques while its structure was confirmed by single crystal X-ray diffraction analysis. The complex has a trigonal bipyramid geometry containing both five- and seven-member chelate rings. It shows catecholase-like activity. Interaction of the complex with a bio-relevant antipyrine derivative (
ANNAP
) was studied using fluorescence spectroscopy. DFT studies unfold the energetics associated with PICPH, [
Cu(PICPH)Cl2
] and the adduct between [
Cu(PICPH)Cl2
] and
ANNAP
. Antimicrobial activities of the compounds were also studied.</description><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpFkM1OwzAQhC0EEqVw4Ql8LKgBO3adhBuK-KsquMA5cuyNMDhxsZ1CH4J3xqhInGalnf20MwidUnJBCasua_G4JDmt2HIPTSgTVVblgu6nmXKekQUXh-gohDdCKC0EnaDvepxhY_AZVq5fW_jCrsMSD_CJTXBm0M4C1uDNRkazgSscoh9VHD3MsZIR1KuzMgC25h2wVMlj4naO5RBNb5R3rZEWr71bg48GQlpo3BqX9YmrRis9NkME_3vphnCMDjppA5z86RS93N481_fZ6unuob5eZSoXPGYKioIoXjBWtIXokiohtSJVrkkuS93plpa8gDbPtZAVryQvBeEsL7tWU75gUzTbcdNnHyOE2PQmKLBWDuDG0NBSlIyVLJGn6HxnTWFC8NA1a2966bcNJc1v581_5-wHEut2Tg</recordid><startdate>2016</startdate><enddate>2016</enddate><creator>Adhikari, Sangita</creator><creator>Lohar, Sisir</creator><creator>Kumari, Babli</creator><creator>Banerjee, Aparna</creator><creator>Bandopadhyay, Rajib</creator><creator>Matalobos, Jesús Sanmartín</creator><creator>Das, Debasis</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0002-9971-4657</orcidid></search><sort><creationdate>2016</creationdate><title>Cu( ii ) complex of a new isoindole derivative: structure, catecholase like activity, antimicrobial properties and bio-molecular interactions</title><author>Adhikari, Sangita ; Lohar, Sisir ; Kumari, Babli ; Banerjee, Aparna ; Bandopadhyay, Rajib ; Matalobos, Jesús Sanmartín ; Das, Debasis</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c264t-ce770c47337b76f733c6adc092d02a8dfdb1847eb22d6a949a48604328fbd1453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Adhikari, Sangita</creatorcontrib><creatorcontrib>Lohar, Sisir</creatorcontrib><creatorcontrib>Kumari, Babli</creatorcontrib><creatorcontrib>Banerjee, Aparna</creatorcontrib><creatorcontrib>Bandopadhyay, Rajib</creatorcontrib><creatorcontrib>Matalobos, Jesús Sanmartín</creatorcontrib><creatorcontrib>Das, Debasis</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Adhikari, Sangita</au><au>Lohar, Sisir</au><au>Kumari, Babli</au><au>Banerjee, Aparna</au><au>Bandopadhyay, Rajib</au><au>Matalobos, Jesús Sanmartín</au><au>Das, Debasis</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cu( ii ) complex of a new isoindole derivative: structure, catecholase like activity, antimicrobial properties and bio-molecular interactions</atitle><jtitle>New journal of chemistry</jtitle><date>2016</date><risdate>2016</risdate><volume>40</volume><issue>12</issue><spage>10094</spage><epage>10099</epage><pages>10094-10099</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>An isoindole based Cu(
ii
) complex, [
Cu(PICPH)Cl2
], was synthesized
in situ
by reacting copper(
ii
) chloride with a pyridine derived ligand, PICPH. The complex was characterized by spectroscopic techniques while its structure was confirmed by single crystal X-ray diffraction analysis. The complex has a trigonal bipyramid geometry containing both five- and seven-member chelate rings. It shows catecholase-like activity. Interaction of the complex with a bio-relevant antipyrine derivative (
ANNAP
) was studied using fluorescence spectroscopy. DFT studies unfold the energetics associated with PICPH, [
Cu(PICPH)Cl2
] and the adduct between [
Cu(PICPH)Cl2
] and
ANNAP
. Antimicrobial activities of the compounds were also studied.</abstract><doi>10.1039/C6NJ02193J</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-9971-4657</orcidid></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Cu( ii ) complex of a new isoindole derivative: structure, catecholase like activity, antimicrobial properties and bio-molecular interactions |
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