High energy density MnO4-/MnO42- redox couple for alkaline redox flow batteries

The MnO4-/MnO42- redox couple has a positive redox potential, high electrochemical reversibility and high solubility, up to 3.62 M at room temperature. Careful optimization of the electrolyte composition and the potential limits eliminates the side reactions, making this redox couple an attractive o...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-11, Vol.52 (97), p.14039-14042
Hauptverfasser: Colli, Alejandro N, Peljo, Pekka, Girault, Hubert H
Format: Artikel
Sprache:eng
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Zusammenfassung:The MnO4-/MnO42- redox couple has a positive redox potential, high electrochemical reversibility and high solubility, up to 3.62 M at room temperature. Careful optimization of the electrolyte composition and the potential limits eliminates the side reactions, making this redox couple an attractive option for alkaline redox flow batteries.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc08070g