Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of ThreeN and Two OAtoms into C sub(60)

A 14-membered heterocycle is created on the C sub(60) cage skeleton through a multistep procedure. Key steps involve repeated PCl sub(5)-induced hydroxylamino N-O bond cleavage leading to insertion of nitrogen atoms, and also piperidine-induced peroxo O-O bond cleavage leading to insertion of oxygen...

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Veröffentlicht in:	Angewandte Chemie 2016-11, Vol.128 (47), p.14810-14814
Hauptverfasser:	Li, Yanbang, Zhang, Gaihong, Wang, Dian, Xu, Beidi, Xu, Dan, Lou, Ning, Gan, Liangbing
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Buckminsterfullerene Cage Carbon Cleavage Fullerenes Insertion Nitrogen atoms
Online-Zugang:	Volltext
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