Frontispiece: Rhodium-Catalyzed Hydrogen-Releasing ortho-Alkenylation of 7-Azaindoles

Frontispiece: Rhodium-Catalyzed Hydrogen-Releasing ortho-Alkenylation of 7-Azaindoles

Rhodium Catalysis An efficient rhodium‐catalyzed dehydrogenative Heck‐type reaction (DHR) between N‐aryl substituted 7‐azaindoles and various alkenes through a H2‐releasing process without the need of any oxidizing agent was developed. This atom‐economical and environmentally friendly DHR method bro...

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Veröffentlicht in:Chemistry : a European journal 2016-12, Vol.22 (50), p.n/a
Hauptverfasser: Li, Wei-Huan, Wu, Lin, Li, Shuai-Shuai, Liu, Chen-Fei, Zhang, Guo-Tai, Dong, Lin
Format: Artikel
Sprache:eng
Schlagworte:
7-azaindoles
Alkenes
Aluminum
Catalysis
Chemistry
Dehydrogenation
hydrogen-releasing
olefin
ortho-alkenylation
Oxidizing agents
Rhodium
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Zusammenfassung:Rhodium Catalysis An efficient rhodium‐catalyzed dehydrogenative Heck‐type reaction (DHR) between N‐aryl substituted 7‐azaindoles and various alkenes through a H2‐releasing process without the need of any oxidizing agent was developed. This atom‐economical and environmentally friendly DHR method broadens the scope of metal‐catalyzed hydrogen‐releasing reactions to include rhodium catalysis. For more details, see the Communication by L. Dong et al. on page 17926 ff.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201685061