Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl)

Free radical polymerization of B-vinyl- and B-styryl-functionalized azaborinine monomers gives well-defined hybrid polymers that were fully characterized by multinuclear NMR and GPC analysis; their solubility, thermal characteristics, and photophysical properties are dramatically different from thos...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (93), p.13616-13619
Hauptverfasser: Wan, Wen-Ming, Baggett, Andrew W, Cheng, Fei, Lin, Huina, Lamm, Ashley N, Liu, Shih-Yuan, Jäkle, Frieder
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Sprache:eng
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Zusammenfassung:Free radical polymerization of B-vinyl- and B-styryl-functionalized azaborinine monomers gives well-defined hybrid polymers that were fully characterized by multinuclear NMR and GPC analysis; their solubility, thermal characteristics, and photophysical properties are dramatically different from those of the all-carbon polystyrene analogues.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc07332h