A highly stable amino-coordinated MOF for unprecedented block off N2 adsorption and extraordinary CO2/N2 separation

A highly stable amino-coordinated metal-organic framework ZJU-198 has been synthesized and structurally characterized, exhibiting high CO2 uptake of 105.8 cm3 cm-3 while blocking off N2 adsorption at 1.0 bar and 298 K, attributed to the unique pore window sizes.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2016-11, Vol.52 (93), p.13568-13571
Hauptverfasser:	Zhang, Ling, Jiang, Ke, Jiang, Mengdie, Yue, Dan, Wan, Yating, Xing, Huabin, Yang, Yu, Cui, Yuanjing, Chen, Banglin, Qian, Guodong
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption Blocking Carbon dioxide Metal-organic frameworks Porosity Separation Synthesis Uptakes
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A highly stable amino-coordinated metal-organic framework ZJU-198 has been synthesized and structurally characterized, exhibiting high CO2 uptake of 105.8 cm3 cm-3 while blocking off N2 adsorption at 1.0 bar and 298 K, attributed to the unique pore window sizes.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c6cc07858c