Nanoparticle-polymer composite volume holographic gratings dispersed with ultrahigh-refractive-index hyperbranched polymer as organic nanoparticles

We report on volume holographic recording at a wavelength of 532 nm in photopolymerizable polymer nanocomposites that are incorporated with new hyperbranched polymers (HBPs) acting as transporting organic nanoparticles. Since HBPs possess an ultrahigh index of refraction of 1.82 due to the inclusion of triazine and aromatic ring units, high-contrast transmission volume holographic gratings with refractive index modulation amplitudes as large as 2.2×10(-2) are recorded. This value enables us to realize a 10 μm thick transmission volume grating with the diffraction efficiency near 100% in the green.