Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformation

Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformation

Herein we report a water-induced single-crystal to single-crystal transformation that involves the formation of hetero-bimetallic paddlewheel clusters in coordination polymers. Through this transformation, which involves the cleavage and formation of different coordination bonds, two different Cu(ii...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (91), p.13397-13400
Hauptverfasser: Albalad, Jorge, Aríñez-Soriano, Javier, Vidal-Gancedo, José, Lloveras, Vega, Juanhuix, Jordi, Imaz, Inhar, Aliaga-Alcalde, Núria, Maspoch, Daniel
Format: Artikel
Sprache:eng
Schlagworte:
Chemical bonds
Cleavage
Clusters
Coordination polymers
Formations
Single crystals
Transformations
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Zusammenfassung:Herein we report a water-induced single-crystal to single-crystal transformation that involves the formation of hetero-bimetallic paddlewheel clusters in coordination polymers. Through this transformation, which involves the cleavage and formation of different coordination bonds, two different Cu(ii)-Zn(ii) and Cu(ii)-Ni(ii) paddlewheel units exhibiting a 1 : 1 metal ratio were created.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc07653j