From Solutions to Surfaces: A Novel Molecular Imprinting Method Based on the Conformational Changes of Boronic-Acid-Appended Poly(L-lysine)

The dominant solution‐phase conformation of a polymer can be fixed to a surface (see scheme). Boronic acid appended poly(L‐lysine) assumes different conformations in the presence of D‐glucose or D‐fructose. When the polymer–glucose complex is anchored to a gold surface, an imprinted interface with “...

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Veröffentlicht in:	Angewandte Chemie International Edition 2001-12, Vol.40 (24), p.4729-4731
Hauptverfasser:	Friggeri, Arianna, Kobayashi, Hideki, Shinkai, Seiji, Reinhoudt, David N.
Format:	Artikel
Sprache:	eng
Schlagworte:	carbohydrates molecular recognition surface chemistry
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description	The dominant solution‐phase conformation of a polymer can be fixed to a surface (see scheme). Boronic acid appended poly(L‐lysine) assumes different conformations in the presence of D‐glucose or D‐fructose. When the polymer–glucose complex is anchored to a gold surface, an imprinted interface with “molecular memory” for glucose over fructose can be prepared.
doi_str_mv	10.1002/1521-3773(20011217)40:24<4729::AID-ANIE4729>3.0.CO;2-M
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subjects	carbohydrates molecular recognition surface chemistry
title	From Solutions to Surfaces: A Novel Molecular Imprinting Method Based on the Conformational Changes of Boronic-Acid-Appended Poly(L-lysine)
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