Selectivity in Propene Polymerization with Metallocene Catalysts

Selectivity in Propene Polymerization with Metallocene Catalysts

The outstandingly rapid scientific and technological development of metallocene-based catalysts for olefin polymerization is a perfect example of the successful application of organometallic chemistry to homogeneous catalysis. The polymerization of propene and higher 1-olefins, however, introduces t...

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Veröffentlicht in:Chemical reviews 2000-04, Vol.100 (4), p.1253-1346
Hauptverfasser: Resconi, Luigi, Cavallo, Luigi, Fait, Anna, Piemontesi, Fabrizio
Format: Artikel
Sprache:eng
Schlagworte:
Catalysts
Chemistry
Metals
Polymers
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Zusammenfassung:The outstandingly rapid scientific and technological development of metallocene-based catalysts for olefin polymerization is a perfect example of the successful application of organometallic chemistry to homogeneous catalysis. The polymerization of propene and higher 1-olefins, however, introduces the problems of stereoselectivity and regio-selectivity.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr9804691