4,5-Bis(diphenylphosphinoyl)-1,2,3-triazole: A Powerful New Ligand That Uses Two Different Modes of Chelation

4,5-Bis(diphenylphosphinoyl)-1,2,3-triazole: A Powerful New Ligand That Uses Two Different Modes of Chelation

The chelation mode selected by the anion of 4,5‐bis(diphenylphosphinoyl)‐1,2,3‐triazole, which is the prototype of a powerful and very stable novel ligand class, is dependent on the metal ion to be coordinated (see scheme).

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2000-09, Vol.39 (18), p.3321-3324
Hauptverfasser: Rheingold, Arnold L., Liable-Sands, Louise M., Trofimenko, Swiatoslaw
Format: Artikel
Sprache:eng
Schlagworte:
coordination modes
ligand effects
N ligands
nitrogen heterocycles
P ligands
phosphonate complexes
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Beschreibung
Zusammenfassung:The chelation mode selected by the anion of 4,5‐bis(diphenylphosphinoyl)‐1,2,3‐triazole, which is the prototype of a powerful and very stable novel ligand class, is dependent on the metal ion to be coordinated (see scheme).
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20000915)39:18<3321::AID-ANIE3321>3.0.CO;2-V