beta relaxation of nonpolymeric liquids close to the glass transition

Dielectric beta relaxation in a pyridine-toluene solution is studied close to the glass transition. Loss peak frequency and maximum loss both exhibit thermal hysteresis. An annealing-state-independent parameter involving loss and loss peak frequency is identified. This parameter has a simple Arrheni...

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Veröffentlicht in:Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics Statistical physics, plasmas, fluids, and related interdisciplinary topics, 2000-09, Vol.62 (3 Pt B), p.4435-4438
Hauptverfasser: Olsen, NB, Christensen, T, Dyre, JC
Format: Artikel
Sprache:eng
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Zusammenfassung:Dielectric beta relaxation in a pyridine-toluene solution is studied close to the glass transition. Loss peak frequency and maximum loss both exhibit thermal hysteresis. An annealing-state-independent parameter involving loss and loss peak frequency is identified. This parameter has a simple Arrhenius temperature dependence. The same behavior is found for four other viscous liquids, indicating that the phenomenon is possibly general.
ISSN:1063-651X
1095-3787
DOI:10.1103/PhysRevE.62.4435