NEt4OH.5H2O containing hydroxide-water layers

In the title compound, tetraethylammonium hydroxide pentahydrate, C(8)H(20)N(+).OH(-).5H(2)O, layers of approximately hexagonally close-packed NEt(4)(+) cations and anionic layers of hydroxide and water molecules are stacked alternately along the b axis. All hydroxide and water H atoms are in ordere...

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Veröffentlicht in:	Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2000-08, Vol.56, p.1050-1052
Hauptverfasser:	WIEBCKE, M, FELSCHE, J
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic, non-condensed and condensed benzenic, and alicyclic compounds Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic compounds Physics Structure of solids and liquids crystallography Structure of specific crystalline solids
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	In the title compound, tetraethylammonium hydroxide pentahydrate, C(8)H(20)N(+).OH(-).5H(2)O, layers of approximately hexagonally close-packed NEt(4)(+) cations and anionic layers of hydroxide and water molecules are stacked alternately along the b axis. All hydroxide and water H atoms are in ordered positions, giving rise to a network of hydrogen bonds [O.O 2.633 (1)-2.947 (2) A] with four- and six-membered rings. The hydroxide ion accepts four hydrogen bonds from four water molecules but does not act as a proton donor.
ISSN:	0108-2701 1600-5759