A three-dimensional network of cadmium

A three-dimensional network of cadmium

The title complex, poly­[bis­[N‐(2‐amino­ethyl)‐N‐methyl‐1,2‐ethane­di­amine]­hexa‐μ‐thio­cyanato‐tricadmium(II) monohydrate], [Cd3(NCS)6(medien)2]n·nH2O [medien is N,N‐bis(2‐amino­ethyl)­methyl­amine, C5H16N3], adopts a three‐dimensional inorganic polymeric network structure. Two cadmium centres (C...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2000-02, Vol.56 (2), p.146-148
Hauptverfasser: Mostafa, Golam, Mondal, Arunendu, Laskar, Inamur R., Welch, A. J., Ray Chaudhuri, N.
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Zusammenfassung:The title complex, poly­[bis­[N‐(2‐amino­ethyl)‐N‐methyl‐1,2‐ethane­di­amine]­hexa‐μ‐thio­cyanato‐tricadmium(II) monohydrate], [Cd3(NCS)6(medien)2]n·nH2O [medien is N,N‐bis(2‐amino­ethyl)­methyl­amine, C5H16N3], adopts a three‐dimensional inorganic polymeric network structure. Two cadmium centres (Cd1 and Cd2) are linked to each other via thio­cyanate bridges. The environment of the Cd1 atom involves only S atoms, making it soft, whereas the environment of the Cd2 atom involves only N atoms, making it hard.
ISSN:0108-2701
1600-5759
DOI:10.1107/S010827019901269X