Chemically Triggered Assembly of Chiral Triangular Metallomacrocycles

Chemically Triggered Assembly of Chiral Triangular Metallomacrocycles

Self‐assembly of chiral, half‐sandwich complexes results in the formation of triangular metallomacrocycles under complete stereocontrol and in quantitative yields. The assembly–disassembly process can be triggered by the addition of acid or base (see scheme).

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Veröffentlicht in:Angewandte Chemie International Edition 1999-11, Vol.38 (21), p.3225-3228
Hauptverfasser: Habereder, Tassilo, Warchhold, Marcus, Nöth, Heinrich, Severin, Kay
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Chiral recognition
Formations
Iridium
Metallacycles
Ruthenium
Self assembly
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container_end_page 3228
container_issue 21
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container_title Angewandte Chemie International Edition
container_volume 38
creator Habereder, Tassilo
Warchhold, Marcus
Nöth, Heinrich
Severin, Kay
description Self‐assembly of chiral, half‐sandwich complexes results in the formation of triangular metallomacrocycles under complete stereocontrol and in quantitative yields. The assembly–disassembly process can be triggered by the addition of acid or base (see scheme).
doi_str_mv 10.1002/(SICI)1521-3773(19991102)38:21<3225::AID-ANIE3225>3.0.CO;2-Q
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source Wiley Online Library Journals Frontfile Complete
subjects Assembly
Chiral recognition
Formations
Iridium
Metallacycles
Ruthenium
Self assembly
title Chemically Triggered Assembly of Chiral Triangular Metallomacrocycles
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