Chemically Triggered Assembly of Chiral Triangular Metallomacrocycles

Chemically Triggered Assembly of Chiral Triangular Metallomacrocycles

Self‐assembly of chiral, half‐sandwich complexes results in the formation of triangular metallomacrocycles under complete stereocontrol and in quantitative yields. The assembly–disassembly process can be triggered by the addition of acid or base (see scheme).

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Veröffentlicht in:Angewandte Chemie International Edition 1999-11, Vol.38 (21), p.3225-3228
Hauptverfasser: Habereder, Tassilo, Warchhold, Marcus, Nöth, Heinrich, Severin, Kay
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Chiral recognition
Formations
Iridium
Metallacycles
Ruthenium
Self assembly
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Beschreibung
Zusammenfassung:Self‐assembly of chiral, half‐sandwich complexes results in the formation of triangular metallomacrocycles under complete stereocontrol and in quantitative yields. The assembly–disassembly process can be triggered by the addition of acid or base (see scheme).
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19991102)38:21<3225::AID-ANIE3225>3.0.CO;2-Q