Intermolecular Hydroamination of Alkynes Catalyzed by Dimethyltitanocene

Intermolecular Hydroamination of Alkynes Catalyzed by Dimethyltitanocene

A completely new application of dimethyltitanocene as catalyst for the intermolecular hydroamination of alkynes is presented. With this inexpensive and readily available catalyst, alkynes can be easily converted into imines, amines, and ketones (see reaction scheme).

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 1999-11, Vol.38 (22), p.3389-3391
Hauptverfasser: Haak, Edgar, Bytschkov, Igor, Doye, Sven
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes
Aminations
Metallocenes
Synthetic methods
Titanium
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Beschreibung
Zusammenfassung:A completely new application of dimethyltitanocene as catalyst for the intermolecular hydroamination of alkynes is presented. With this inexpensive and readily available catalyst, alkynes can be easily converted into imines, amines, and ketones (see reaction scheme).
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19991115)38:22<3389::AID-ANIE3389>3.0.CO;2-E