Effects of open inelastic channels in the resonant dissociative recombination of HeH

We show that {ital ab} {ital initio} theory provides a quantitative description of resonant dissociative recombination. Using a variational method for the electronic scattering problem and a wave packet treatment of the dissociation dynamics, we obtain excellent agreement with recent absolute cross...

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Veröffentlicht in:Physical Review Letters 1995-06, Vol.74 (24), p.4807-4810
Hauptverfasser: Orel, AE, Kulander, KC, Rescigno, TN
Format: Artikel
Sprache:eng
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Zusammenfassung:We show that {ital ab} {ital initio} theory provides a quantitative description of resonant dissociative recombination. Using a variational method for the electronic scattering problem and a wave packet treatment of the dissociation dynamics, we obtain excellent agreement with recent absolute cross sections for dissociative recombination of {sup 3}HeH{sup +} in the 10--30 eV region. The cross section contains significant contributions from several resonance states, some of which autoionize into electronically excited states. A proper multichannel treatment of the resonances is needed to achieve quantitative agreement with experiment.
ISSN:0031-9007
1079-7114
DOI:10.1103/PhysRevLett.74.4807