Effects of open inelastic channels in the resonant dissociative recombination of HeH
We show that {ital ab} {ital initio} theory provides a quantitative description of resonant dissociative recombination. Using a variational method for the electronic scattering problem and a wave packet treatment of the dissociation dynamics, we obtain excellent agreement with recent absolute cross...
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Veröffentlicht in: | Physical Review Letters 1995-06, Vol.74 (24), p.4807-4810 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | We show that {ital ab} {ital initio} theory provides a quantitative description of resonant dissociative recombination. Using a variational method for the electronic scattering problem and a wave packet treatment of the dissociation dynamics, we obtain excellent agreement with recent absolute cross sections for dissociative recombination of {sup 3}HeH{sup +} in the 10--30 eV region. The cross section contains significant contributions from several resonance states, some of which autoionize into electronically excited states. A proper multichannel treatment of the resonances is needed to achieve quantitative agreement with experiment. |
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ISSN: | 0031-9007 1079-7114 |
DOI: | 10.1103/PhysRevLett.74.4807 |