Observation of two-dimensional compositional ordering of a carbon monoxide and argon monolayer mixture physisorbed on graphite
Commensurate monolayers of a mixture of 70% carbon monoxide and 30% argon on graphite are studied by neutron and low-energy-electron diffraction. A 2 x 2 superstructure due to 3:1 compositional ordering is observed below 25 K. The compositional ordering is most likely due to molecular-axis ordering...
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Veröffentlicht in: | Phys. Rev. Lett.; (United States) 1986-01, Vol.56 (3), p.244-247 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Commensurate monolayers of a mixture of 70% carbon monoxide and 30% argon on graphite are studied by neutron and low-energy-electron diffraction. A 2 x 2 superstructure due to 3:1 compositional ordering is observed below 25 K. The compositional ordering is most likely due to molecular-axis ordering of carbon monoxide molecules into a pinwheel pattern with argon atoms at the central sites of each pinwheel. Such a pinwheel structure has been predicted by Harris, Mouritsen, and Berlinsky for planar rotors with anisotropic interactions on a triangular lattice with vacancies. |
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ISSN: | 0031-9007 1079-7114 |
DOI: | 10.1103/PhysRevLett.56.244 |