Recent Methodologies That Exploit C–C Single-Bond Cleavage of Strained Ring Systems by Transition Metal Complexes

In this review, synthetic and mechanistic aspects of key methodologies that exploit C–C single-bond cleavage of strained ring systems are highlighted. The focus is on transition-metal-catalyzed processes that are triggered by C–C bond activation and β-carbon elimination, with the review concentratin...

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Veröffentlicht in:Chemical reviews 2017-07, Vol.117 (13), p.9404-9432
Hauptverfasser: Fumagalli, Gabriele, Stanton, Steven, Bower, John F
Format: Artikel
Sprache:eng
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Zusammenfassung:In this review, synthetic and mechanistic aspects of key methodologies that exploit C–C single-bond cleavage of strained ring systems are highlighted. The focus is on transition-metal-catalyzed processes that are triggered by C–C bond activation and β-carbon elimination, with the review concentrating on developments from mid-2009 to mid-2016.
ISSN:0009-2665
1520-6890
DOI:10.1021/acs.chemrev.6b00599