An N-(acetoxy)phthalimide motif as a visible-light pro-photosensitizer in photoredox decarboxylative arylthiation

An N-(acetoxy)phthalimide motif as a visible-light pro-photosensitizer in photoredox decarboxylative arylthiation

An efficient visible-light photoredox decarboxylative coupling of N-(acetoxy)phthalimides with aryl thiols has been developed. The reaction was performed well at room temperature with good tolerance of functional groups. Importantly, the visible-light photoredox decarboxylative arylthiation did not...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (87), p.12909-12912
Hauptverfasser: Jin, Yunhe, Yang, Haijun, Fu, Hua
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic compounds
Coupling
Functional groups
Photocatalysis
Photocatalysts
Thiols
Tolerances
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Zusammenfassung:An efficient visible-light photoredox decarboxylative coupling of N-(acetoxy)phthalimides with aryl thiols has been developed. The reaction was performed well at room temperature with good tolerance of functional groups. Importantly, the visible-light photoredox decarboxylative arylthiation did not need an added photocatalyst.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc06994k