Trends of perchlorate in Antarctic snow: Implications for atmospheric production and preservation in snow

Perchlorate concentration ranges from a few to a few hundred ng kg−1 in surface and shallow‐depth snow at three Antarctic locations (South Pole, Dome A, and central West Antarctica), with significant spatial variations dependent on snow accumulation rate and/or atmospheric production rate. An obvious trend of increasing perchlorate since the 1970s is seen in South Pole snow. The trend is possibly the result of stratospheric chlorine levels elevated by anthropogenic chlorine emissions; this is supported by the timing of a similar trend at Dome A. Alternatively, the trend may stem from postdepositional loss of snowpack perchlorate or a combination of both. The possible impact of stratospheric chlorine is consistent with evidence of perchlorate production in the stratosphere. Additionally, perchlorate concentration appears to be directly affected by the springtime Antarctic ozone hole. Therefore, perchlorate variations in Antarctic snow are likely linked to stratospheric chemistry and ozone over the Antarctic. Key Points Perchlorate data display decreasing pattern with depth suggesting variation in source(s) and/or postdepositional loss in Antarctic snow Perchlorate production is largely influenced by stratospheric ozone and stratospheric chlorine Anthropogenic emissions of chlorine compounds may have caused perchlorate production over Antarctica to increase tenfold since the 1970s