High CO2 Uptake Capacity and Selectivity in a Fascinating Nanotube-Based Metal–Organic Framework

High CO2 Uptake Capacity and Selectivity in a Fascinating Nanotube-Based Metal–Organic Framework

An unusual porous metal–organic framework has been synthesized by using Pb­(II) and rigid V-shaped 4,4′-(pyri­dine-3,5-diyl)­diiso­phthalic acid (H4L). Structure analysis reveals that there exist 1D cylindrical 14.26 Å and triangular prism 10.69 × 10.69 × 10.69 Å3 nanotubes in the framework. Gas sor...

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Veröffentlicht in:Inorganic chemistry 2017-01, Vol.56 (2), p.908-913
Hauptverfasser: Wu, Yun-Long, Qian, Jinjie, Yang, Guo-Ping, Yang, Fan, Liang, Yu-Tong, Zhang, Wen-Yan, Wang, Yao-Yu
Format: Artikel
Sprache:eng
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Zusammenfassung:An unusual porous metal–organic framework has been synthesized by using Pb­(II) and rigid V-shaped 4,4′-(pyri­dine-3,5-diyl)­diiso­phthalic acid (H4L). Structure analysis reveals that there exist 1D cylindrical 14.26 Å and triangular prism 10.69 × 10.69 × 10.69 Å3 nanotubes in the framework. Gas sorption behavior of the nanoporous MOF shows a relatively high capacity and selectivity of CO2 over CH4.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.6b02491