Preparation of tungsten carbide nanosheets with large surface area using an in situ DWCNT template

Tungsten carbide (WC) nanosheets were prepared using an in situ double-walled carbon nanotube (DWCNT) template with high dispersion. The growth of tungstenic acid (H 2 WO 4 ) was restrained because of homogenous DWCNTs that were dispersed in ethylene glycol (EG). H 2 WO 4 sheets approximately 50 nm...

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Veröffentlicht in:RSC advances 2014-01, Vol.4 (88), p.47414-47420
Hauptverfasser: Wu, Zi Ping, Zhao, Man, Hu, Jing Wei, Zhang, Wei Bo, Yin, Yan Hong, Hu, Ying Yan, Li, Ye Sheng, Yang, Jian Gao, Xu, Qian Feng, Krishamurthy, Ajay
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Sprache:eng
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Zusammenfassung:Tungsten carbide (WC) nanosheets were prepared using an in situ double-walled carbon nanotube (DWCNT) template with high dispersion. The growth of tungstenic acid (H 2 WO 4 ) was restrained because of homogenous DWCNTs that were dispersed in ethylene glycol (EG). H 2 WO 4 sheets approximately 50 nm long and 20 nm wide were obtained. WC nanosheets with large surface areas were prepared when the tungstenic precursor was carbonized at a low temperature using a liquid carbon source. The WC was used as a precursor for depositing Pt nanoparticles, and the obtained WC–Pt displayed a high electrochemical activity (Pt, 10 wt%). The results indicated that WC with a peculiar morphology and size could be used in electrochemistry, horniness alloys, and in other related fields.
ISSN:2046-2069
2046-2069
DOI:10.1039/C4RA08029G