Emerging Roles of in Situ Generated Quinone Methides in Metal-Free Catalysis

ortho-Quinone methides have emerged recently as useful electrophiles in metal-free catalysis. New strategies to access these species in situ that are compatible with simultaneous nucleophile generation have provided a suite of innovative and selective transformations accessing heterocycles for use i...

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Veröffentlicht in:Journal of organic chemistry 2016-11, Vol.81 (21), p.10145-10153
Hauptverfasser: Jaworski, Ashley A, Scheidt, Karl A
Format: Artikel
Sprache:eng
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Zusammenfassung:ortho-Quinone methides have emerged recently as useful electrophiles in metal-free catalysis. New strategies to access these species in situ that are compatible with simultaneous nucleophile generation have provided a suite of innovative and selective transformations accessing heterocycles for use in organic synthesis.
ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.6b01367