In Situ Synthesis of Metal Sulfide Nanoparticles Based on 2D Metal-Organic Framework Nanosheets

In Situ Synthesis of Metal Sulfide Nanoparticles Based on 2D Metal-Organic Framework Nanosheets

A facile in situ synthetic method is developed to synthesize metal sulfide nanoparticles based on 2D M‐TCPP (M = Cu, Cd, or Co, TCPP = tetrakis(4‐carboxyphenyl)porphyrin)) metal‐organic framework nanosheets. The obtained CuS/Cu‐TCPP composite nanosheet is used as the active material in photoelectroc...

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Veröffentlicht in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2016-09, Vol.12 (34), p.4669-4674
Hauptverfasser: Lu, Qipeng, Zhao, Meiting, Chen, Junze, Chen, Bo, Tan, Chaoliang, Zhang, Xiao, Huang, Ying, Yang, Jian, Cao, Feifei, Yu, Yifu, Ping, Jianfeng, Zhang, Zhicheng, Wu, Xue-Jun, Zhang, Hua
Format: Artikel
Sprache:eng
Schlagworte:
composites
metal sulfide nanoparticles
Metal sulfides
Metal-organic frameworks
Nanoparticles
nanosheets
Nanostructure
Nanotechnology
Particulate composites
Photocurrent
photoelectrochemical cells
Photoelectrochemical devices
Two dimensional
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Beschreibung
Zusammenfassung:A facile in situ synthetic method is developed to synthesize metal sulfide nanoparticles based on 2D M‐TCPP (M = Cu, Cd, or Co, TCPP = tetrakis(4‐carboxyphenyl)porphyrin)) metal‐organic framework nanosheets. The obtained CuS/Cu‐TCPP composite nanosheet is used as the active material in photoelectrochemical cells, showing notably increased photocurrent due to the improved exciton separation and charge carrier transport.
ISSN:1613-6810
1613-6829
DOI:10.1002/smll.201600976