Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen

Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen

Domino reactions of ketones with molecular oxygen in the presence of potassium hydroxide and potassium t -butoxide afford cyclic hydroperoxy acetals (3,5-dihydroxy-1,2-dioxanes). Mixed endoperoxides can also be obtained in a three-component reaction of two ketones and oxygen.

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Veröffentlicht in:RSC advances 2015-01, Vol.5 (120), p.99577-99584
Hauptverfasser: Novkovic, L., Trmcic, M., Rodic, M., Bihelovic, F., Zlatar, M., Matovic, R., Saicic, R. N.
Format: Artikel
Sprache:eng
Schlagworte:
Acetals
Cascade chemical reactions
Ketones
Oxygen
Potassium
Potassium hydroxides
Synthesis (chemistry)
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Zusammenfassung:Domino reactions of ketones with molecular oxygen in the presence of potassium hydroxide and potassium t -butoxide afford cyclic hydroperoxy acetals (3,5-dihydroxy-1,2-dioxanes). Mixed endoperoxides can also be obtained in a three-component reaction of two ketones and oxygen.
ISSN:2046-2069
2046-2069
DOI:10.1039/C5RA13476E