CO2 capture enhancement in InOF-1 via the bottleneck effect of confined ethanol

CO2 capture enhancement in InOF-1 via the bottleneck effect of confined ethanol

CO2 capture of InOF-1 was enhanced 3.6-fold, at 1 bar and 30 °C, by confining EtOH within its pores. Direct visualisation by single crystal X-ray diffraction revealed that EtOH divides InOF-1 channels in wide sections separated by "bottlenecks" caused by EtOH molecules bonded to the μ2-OH...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (67), p.10273-10276
Hauptverfasser: Peralta, Ricardo A, Campos-Reales-Pineda, Alberto, Pfeiffer, Heriberto, Álvarez, J Raziel, Zárate, J Antonio, Balmaseda, Jorge, González-Zamora, Eduardo, Martínez, Ana, Martínez-Otero, Diego, Jancik, Vojtech, Ibarra, Ilich A
Format: Artikel
Sprache:eng
Schlagworte:
Bonding
Carbon capture and storage
Carbon dioxide
Channels
Confining
Diffraction
Ethyl alcohol
X-rays
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Zusammenfassung:CO2 capture of InOF-1 was enhanced 3.6-fold, at 1 bar and 30 °C, by confining EtOH within its pores. Direct visualisation by single crystal X-ray diffraction revealed that EtOH divides InOF-1 channels in wide sections separated by "bottlenecks" caused by EtOH molecules bonded to the μ2-OH functional groups of InOF-1.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc04734c