Rejuvenation of perovskite solar cells

A novel method has been developed to recharge and rejuvenate perovskite solar cells by immersing the device into methyl ammonium iodide (MAI) solution and heating at 70 °C for 40 s. We demonstrated that Au electrodes are more robust than Al and Ag electrodes for ZnO planar structures rather than ZnO...

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Veröffentlicht in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2016-01, Vol.4 (32), p.7595-7600
Hauptverfasser: Huang, Yi-You, Gollavelli, Ganesh, Chao, Yi-Hsiang, Hsu, Chain-Shu
Format: Artikel
Sprache:eng
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Zusammenfassung:A novel method has been developed to recharge and rejuvenate perovskite solar cells by immersing the device into methyl ammonium iodide (MAI) solution and heating at 70 °C for 40 s. We demonstrated that Au electrodes are more robust than Al and Ag electrodes for ZnO planar structures rather than ZnO and TiO 2 nanoparticles (NPs). In addition to this, the degradation mechanism of the device has been discussed. The scanning electron microscopy (SEM) images and X-ray diffraction (XRD) spectroscopy are evidence that the perovskite crystals have been regenerated after degradation (60 days) with the help of MAI as a rejuvenating agent. After long-term aging tests with rejuvenation in 185 days, its PCE value is still around 11% compared to the original one of 11.6%.
ISSN:2050-7526
2050-7534
DOI:10.1039/C6TC02307J