Fully Cationized Gold Clusters: Synthesis of Au25(SR+)18

Fully Cationized Gold Clusters: Synthesis of Au25(SR+)18

Although many thiolate-protected Au clusters with different numbers of Au atoms and a variety of thiolate ligands have been synthesized, to date there has been no report of a fully cationized Au cluster protected with cationic thiolates. Herein, we report the synthesis of the first member of a new s...

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Veröffentlicht in:The journal of physical chemistry letters 2016-10, Vol.7 (19), p.3718-3722
Hauptverfasser: Ishida, Yohei, Narita, Kunihiro, Yonezawa, Tetsu, Whetten, Robert L
Format: Artikel
Sprache:eng
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Zusammenfassung:Although many thiolate-protected Au clusters with different numbers of Au atoms and a variety of thiolate ligands have been synthesized, to date there has been no report of a fully cationized Au cluster protected with cationic thiolates. Herein, we report the synthesis of the first member of a new series of thiolate-protected Au cluster molecules: a fully cationized Au25(SR+)18 cluster.
ISSN:1948-7185
1948-7185
DOI:10.1021/acs.jpclett.6b01725