Widespread polybrominated diphenyl ether (PBDE) contamination of urban soils in Melbourne, Australia

Polybrominated diphenyl ethers (PBDEs) have been used as flame retardants in a variety of materials and products. PBDEs have been shown to accumulate in the environment and human populations while exhibiting a range of toxic effects. In this study, surface soil samples from 30 sites in the city of Melbourne, Australia, were analysed for PBDEs. Eight congeners of environmental concern (BDE-28, -47, -99, -100, -153, -154 -183 and -209) were assessed using selective pressurized liquid extraction (S-PLE) and gas chromatography coupled to triple quadrupole mass spectrometry (GC-MS/MS). PBDEs were detected in 29/30 samples with Σ8PBDE soil concentrations ranging nd-13,200 ng/g dw and Σ7PBDEs (excluding BDE-209) levels of nd-70.5 ng/g dw. Soils from waste disposal sites (n = 6) contained the highest median Σ7PBDE and Σ8PBDE concentrations, followed by manufacturing sites (n = 18) and then non-source sites (n = 6). Electronics recycling facilities contained the greatest levels of Σ8PBDEs by a significant margin (p