Capsoplexes: encapsulating complexes via guest recognition

Capsoplexes: encapsulating complexes via guest recognition

A new dinuclear Ni-NHC complex is able to selectively recognise and self-assemble with guests via tennis-ball like encapsulation, exemplarily demonstrated employing halides. Addition of chloride or bromide leads to the formation of capsules with small cavities which are stabilised through non-classi...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (58), p.9089-9092
Hauptverfasser: Altmann, Philipp J, Pöthig, Alexander
Format: Artikel
Sprache:eng
Schlagworte:
Chlorides
Coulomb friction
Encapsulation
Holes
Hydrogen bonds
Lead (metal)
Nickel
Recognition
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Zusammenfassung:A new dinuclear Ni-NHC complex is able to selectively recognise and self-assemble with guests via tennis-ball like encapsulation, exemplarily demonstrated employing halides. Addition of chloride or bromide leads to the formation of capsules with small cavities which are stabilised through non-classical hydrogen bonds and Coulomb interactions between the anion and the metal centres.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc00507a