Synthesis and optical properties of novel Tröger's base derivatives

Synthesis and optical properties of novel Tröger's base derivatives

Diphenylamine, phenothiazine or carbazole were introduced into Tröger's base skeleton via Ullmann or Suzuki coupling to afford new TB derivatives. Their optical properties tests, density functional theory (B3LYP; 6-31G*) calculations were investigated. Incidentally anti-cancer activity against...

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Veröffentlicht in:Tetrahedron 2016-07, Vol.72 (27-28), p.4081-4084
Hauptverfasser: Yuan, Rui, Li, Ming-qi, Xu, Jiang-biao, Huang, Shu-ying, Zhou, Sheng-liang, Zhang, Peng, Liu, Jin-juan, Wu, Hui
Format: Artikel
Sprache:eng
Schlagworte:
Anti-cancer activity
Anticancer properties
Coupling
Density functional theory
Derivatives
Fluorescence
Mathematical analysis
Optical properties
Photoelectric property
Synthesis
Tetrahedrons
Theoretical calculations
Tröger's base derivatives
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Zusammenfassung:Diphenylamine, phenothiazine or carbazole were introduced into Tröger's base skeleton via Ullmann or Suzuki coupling to afford new TB derivatives. Their optical properties tests, density functional theory (B3LYP; 6-31G*) calculations were investigated. Incidentally anti-cancer activity against human hepatoma HepG2 cells in vitro (MTT assay) were investigated. All the results indicated that these novel compounds have the potential as fluorescence materials. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2016.05.042