Synthesis of g-C sub(3)N sub(4) at different temperatures for superior visible/UV photocatalytic performance and photoelectrochemical sensing of MB solution

In this paper, a simple preparation method was utilized to study for the optimum calcination temperature of graphitic carbon nitride (g-C sub(3)N sub(4)). The g-C sub(3)N sub(4) prepared at different temperatures were characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy (DRS) and so on. The results demonstrated that g-C sub(3)N sub(4) could not be formed fully until the calcination temperature was higher than 500 degree C. From DRS and photoluminescence (PL) spectrum, a red shift of absorption peaks with increasing calcination temperatures was found. This could enhance the visible light absorption, and then the photocatalytic activity would be improved. The photocatalytic activity was evaluated viathe photodegradation of methylene blue (MB) and 4-chlorophenol (4-CP), respectively. Moreover, due to the gradual decrement trend of photocurrent intensity with addition of MB, g-C sub(3)N sub(4) prepared at 650 degree C could be used as a photoelectrochemical sensor to detect the existence of MB and estimate the concentration of MB. Hence g-C sub(3)N sub(4) will become a promising candidate for photoelectrochemical applications.