Fabrication and improved performance of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) for packaging by addition of high molecular weight natural rubber

ABSTRACT The packaging industry is searching for alternative materials to attain environmental sustainability. Poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate (PHBV) is a semicrystalline polymer that meets this sustainability goal since it is bioderived and biodegradable. However, its brittle nature and relatively high water permeation and transmission rates make it unsuitable for packaging applications. In addition, PHBV has poor mechanical, thermal, and rheological properties above 160 °C, limiting its use in cast sheets and thermo‐formed packaging applications. To improve these properties, new blends of PHBV with high molecular weight natural rubber at 5, 10, 15, and 25% by weight were fabricated, and physico‐chemical properties of the blends were characterized. The rubber in the blends aided in the following: increased thermal stability since the complex viscosities of the blends were improved by one log over pure PHBV at 170 °C, created more uniform melting peaks attesting to improved homogeneity, decreased water permeation to a level similar to that of traditional thermoplastics; increased the elongation at break, and stabilized the Young's modulus. Therefore, these blends can potentially be used in‐place of traditional, petroleum‐based thermoplastics in cast sheets and thermoforms. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43937.